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Beilstein J. Org. Chem. 2017, 13, 1969–1976, doi:10.3762/bjoc.13.192
Graphical Abstract
Scheme 1: Biogenetic hypothesis for the transformation of schkuhriolide (1) into elemanschkuriolide (3).
Figure 1: Reaction paths M (blue), N (orage), O (yellow) and P (green) for the transformation of 1 into 3. Re...
Scheme 2: Similar compounds to melampolide 1 unable to be hemiacetaled.
Figure 2: Schematic representations of the calculated C5 epimeric structures of 2 and 3. Relative electronic ...
Figure 3: Reaction paths of the Cope rearrangements of closed (dark blue and orange) and open (red and pink) ...